N,N-dialkylcarbamato complexes as precursors for the chemical implantation of metal cations on a silica support .1. Tin

被引：33

作者：

Abis, L

DellAmico, DB

Calderazzo, F

Caminiti, R

Garbassi, F

Ianelli, S

Pelizzi, G

Robino, P

Tomei, A

机构：

[1] UNIV PISA,DIPARTIMENTO CHIM & CHIM IND,SEZ CHIM INORGAN,I-56126 PISA,ITALY

[2] IST GUIDO DONEGANI ENICHEM,I-28100 NOVARA,ITALY

[3] UNIV ROMA LA SAPIENZA,DIPARTIMENTO CHIM,I-00185 ROME,ITALY

[4] UNIV PARMA,IST CHIM GEN,I-43100 PARMA,ITALY

[5] CNR,CTR STUDIO STRUTTURIST DIFFRATTOMETR,I-43100 PARMA,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1996年 / 108卷 / 03期

关键词：

implantation; carbamate; tin; silica; N; N-dialkylcarbamates; SURFACE ORGANOMETALLIC CHEMISTRY; MOLECULAR-STRUCTURE; ALLYL RHODIUM; CRYSTAL; CATALYSIS; ALUMINA; SIO2; ACTIVATION; CARBONYLS; OS3(CO)12;

D O I：

10.1016/1381-1169(96)00032-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Chemical implantation of tin on a commercial silica has been carried out by using the hydrocarbon soluble Sn((O2CNPr2)-Pr-i)(4) as precursor, the N,N-dialkylcarbamato group is chemically displaced by the silanol groups of the support under mild conditions.

引用

页码：L113 / L117

页数：5

共 48 条

[41] ALKANE ACTIVATION BY OXIDE-BOUND ORGANORHODIUM COMPLEXES [J].