Different electrical characterization techniques (subthreshold current-voltage measurements, standard, 3-level and multi-frequency charge pumping) combined with isochronal anneals have been used to investigate the generation and the evolution of interface traps in radiation-hardened MOS transistors following exposure to 10 keV X-rays. The evolution of the interface state density (D-it) during the anneal is found to be field-dependent and consistent with models involving a drift of positive species towards the, Si-SiO2 interface. The energy-resolved distributions of D-it in the silicon bandgap show the emergence of two broad structures located at similar to E(v) + 0.35 eV and similar to E(v) + 0.75 eV immediately after irradiation and during the first steps of the isochronal anneal (up to similar to 175 degrees C). At higher anneal temperatures, it is shown that the recovery of D-it is not uniform in the two halves of the silicon bandgap. In particular, the separation of the D-it distribution related to the lower part of the bandgap in two distinct peaks (at E(v) + 0.30 eV and E(v) + 0.45 eV) agrees well with the energy distributions of P-b0 and P-b1 centers. These results are consistent with Electron Spin Resonance (ESR) studies which have shown that P-b centers play a dominating role in the interface trap build-up and recovery mechanisms. Since ESR measurements are only accurate to similar to +/- 30% in absolute number, P-b centers do not probably account for all the electrically active interface trap defects, as also suggested by the evident asymmetry of the D-it distributions in the bandgap. Finally, we investigate the post-irradiation response of border traps by reducing the charge pumping frequency to low values. The implication of these results on the nature of border traps is discussed.