A chain complex of ruthenium(II,III) cation dimer linked by a nitroxide radical, [Ru-2(O(2)CCMe(3))(4)(NITPh)](n)(BF4)(n) (NITPh=2-phenyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxy-3-oxide)

被引：39

作者：

Handa, M ^{[1
]}

Sayama, Y ^{[1
]}

Mikuriya, M ^{[1
]}

Nukada, R ^{[1
]}

Hiromitsu, I ^{[1
]}

Kasuga, K ^{[1
]}

机构：

[1] SHIMANE UNIV, FAC SCI & ENGN, DEPT MAT SCI, MATSUE, SHIMANE 690, JAPAN

来源：

CHEMISTRY LETTERS | 1996年 / 03期

关键词：

D O I：

10.1246/cl.1996.201

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chain complex of ruthenium(II,III) cation dimer linked by the nitroxide radical, [Ru-2(O(2)CCMe(3))(4)(NITPh)](n)(BF4)(n) (NITPh=2-phenyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-yl-1-oxy-3-oxide) has been prepared and characterized. The structure with the alternated alignment of S=3/2 (Ru(II,III) core) and S=1/2 (NITPh) has been confirmed by the X-ray crystal analysis. The magnetic moment decreases monotonously with decrease of temperature.

引用

页码：201 / 202

页数：2

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