Enantioselective conjugate addition of phenylboronic acid to enones catalysed by a chiral tropos/atropos rhodium complex at the coalescence temperature

被引：43

作者：

Monti, C

Gennari, C

Piarulli, U

机构：

[1] Univ Milan, Ctr Eccellenza CISI, Dipartimento Chim Organ & Ind, ISTM,CNR, I-20133 Milan, Italy

[2] Univ Insubria, Dipartimento Sci Chim & Ambientali, I-22100 Como, Italy

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 42期

关键词：

D O I：

10.1039/b508832a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly enantioselective rhodium-catalysed conjugate addition of phenylboronic acid to cyclic enones has been achieved using a dynamic library of chiral phosphorus ligands; the tropos/atropos nature of the ligands in the rhodium complex has been characterised via P-31-NMR.

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收藏

页码：5281 / 5283

页数：3

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