We herein report the use of a new class of P,O-bidentate arylphosphine ligand for the asymmetric copper catalyzed conjugate addition of dialkylzinc and trialkylaluminium with the enantiomeric excesses reaching 91% while (R)-muscone was obtained with 77% ee. (c) 2005 Elsevier Ltd. All rights reserved.
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[1]
Alexakis A, 1999, SYNLETT, P1811
[2]
Alexakis A, 2002, EUR J ORG CHEM, V2002, P3221
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Univ Paris 06, URA 473 CNRS, Lab Chim Organoelements, F-75252 Paris 05, FranceUniv Paris 06, URA 473 CNRS, Lab Chim Organoelements, F-75252 Paris 05, France
Alexakis, A
Burton, J
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Univ Paris 06, URA 473 CNRS, Lab Chim Organoelements, F-75252 Paris 05, FranceUniv Paris 06, URA 473 CNRS, Lab Chim Organoelements, F-75252 Paris 05, France
Burton, J
Vastra, J
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Univ Paris 06, URA 473 CNRS, Lab Chim Organoelements, F-75252 Paris 05, FranceUniv Paris 06, URA 473 CNRS, Lab Chim Organoelements, F-75252 Paris 05, France
Vastra, J
Mangeney, P
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Univ Paris 06, URA 473 CNRS, Lab Chim Organoelements, F-75252 Paris 05, FranceUniv Paris 06, URA 473 CNRS, Lab Chim Organoelements, F-75252 Paris 05, France
机构:
Univ Paris 06, URA 473 CNRS, Lab Chim Organoelements, F-75252 Paris 05, FranceUniv Paris 06, URA 473 CNRS, Lab Chim Organoelements, F-75252 Paris 05, France
Alexakis, A
Burton, J
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Univ Paris 06, URA 473 CNRS, Lab Chim Organoelements, F-75252 Paris 05, FranceUniv Paris 06, URA 473 CNRS, Lab Chim Organoelements, F-75252 Paris 05, France
Burton, J
Vastra, J
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Univ Paris 06, URA 473 CNRS, Lab Chim Organoelements, F-75252 Paris 05, FranceUniv Paris 06, URA 473 CNRS, Lab Chim Organoelements, F-75252 Paris 05, France
Vastra, J
Mangeney, P
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h-index: 0
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Univ Paris 06, URA 473 CNRS, Lab Chim Organoelements, F-75252 Paris 05, FranceUniv Paris 06, URA 473 CNRS, Lab Chim Organoelements, F-75252 Paris 05, France