Electrochemical preparation of few layer-graphene nanosheets via reduction of oriented exfoliated graphene oxide thin films in acetamide-urea-ammonium nitrate melt under ambient conditions

被引：26

作者：

Dilimon, V. S. ^{[1
]}

Sampath, S. ^{[1
]}

机构：

[1] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India

来源：

THIN SOLID FILMS | 2011年 / 519卷 / 07期

关键词：

Molten electrolyte; Acetamide; Urea; Ammonium nitrate melt; Graphene oxide; Electrochemical reduction; Atomic force microscopy; GRAPHITE OXIDE; RAMAN-SPECTROSCOPY; MONOLAYERS; SHEETS; ELECTRONICS; SPECTRA; CARBON;

D O I：

10.1016/j.tsf.2010.11.019

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Electrochemical reduction of exfoliated graphene oxide, prepared from pre-exfoliated graphite, in acetamide-urea-ammonium nitrate ternary eutectic melt results in few layer-graphene thin films. Negatively charged exfoliated graphene oxide is attached to positively charged cystamine monolyer self-assembled on a gold surface. Electrochemical reduction of the oriented graphene oxide film is carried out in a room temperature, ternary molten electrolyte. The reduced film is characterized by atomic force microscopy (AFM), conductive AFM, Fourier-transform infrared spectroscopy and Raman spectroscopy. Ternary eutectic melt is found to be a suitable medium for the regulated reduction of graphene oxide to reduced graphene oxide-based sheets on conducting surfaces. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：2323 / 2327

页数：5

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