Aerobic oxidation of benzyl alcohol catalyzed by Cu-Mn mixed oxides and 2,2,6,6-tetramethyl-piperidyl-1-oxyl

被引：22

作者：

Guo, Yanchun ^{[1
]}

Zhao, Junfeng ^{[2
]}

Xu, Jinxia ^{[1
]}

Wang, Wei ^{[1
]}

Tian, Fengshou ^{[1
]}

Yang, Guanyu ^{[1
]}

Song, Maoping ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Henan, Peoples R China

[2] Zhengzhou Econ Management Inst, Dept Environm Engn, Zhengzhou 451191, Henan, Peoples R China

来源：

JOURNAL OF NATURAL GAS CHEMISTRY | 2007年 / 16卷 / 02期

关键词：

Cu-Mn oxides; 2,2,6,6-tetrainethyl-piperidyl-1-oxyl aerobic oxidation; benzyl alcohol;

D O I：

10.1016/S1003-9953(07)60050-4

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Heterogeneous Cu-Mn mixed oxides can mediate TEMPO-catalyzed selective oxidation of benzyl alcohol by molecular oxygen under neutral condition, and is recyclable. In the case of the molar ratio of Cu and Mn over 1, the highly-dispersed CuO inside the Cu-Mn mixed oxides is responsible for the good performances in catalytic oxidation.

引用

页码：210 / 212

页数：3

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