Synthesis and cycloaromatization kinetics of aromatic allene enynes

被引：27

作者：

Dopico, PG ^{[1
]}

Finn, MG ^{[1
]}

机构：

[1] Univ Virginia, Dept Chem, Charlottesville, VA 22901 USA

来源：

TETRAHEDRON | 1999年 / 55卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4020(98)01022-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aryl- and cyclopropyl-substituted allene enynes were prepared by a double olefination procedure from various aldehydes, and their cycloaromatization reactions were subjected to kinetics measurements in methanol and 1,4-cyclohexadiene solvents. The results support previous proposals of a polar diradical transition state for the cycloaromatization process. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：29 / 62

页数：34

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