Direct Addition of Functionalized Organozinc Reagents to Carbon Dioxide, Ketones, and Aldehydes in the Presence of MgCl2

被引：22

作者：

Bernhardt, Sebastian ^{[1
]}

Metzger, Albrecht ^{[1
]}

Knochel, Paul ^{[1
]}

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

SYNTHESIS-STUTTGART | 2010年 / 22期

基金：

欧洲研究理事会;

关键词：

organozinc reagents; magnesium chloride; carbon dioxide; phenylacetic acid derivatives; addition reactions; BENZYLIC ZINC CHLORIDES; DIRECT INSERTION; LICL; MAGNESIUM; BROMIDES; HALIDES; ARYLZINC; DIETHYL; COBALT; ZNCL2;

D O I：

10.1055/s-0030-1258314

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学];

摘要：

A variety of functionalized organozinc reagents undergo smooth addition reactions at ambient temperature to carbon dioxide, ketones, and aldehydes in the presence of stoichiometric amounts of MgCl2. Several reactions were performed on a 20 mmol scale.

引用

收藏

页码：3802 / 3810

页数：9

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