Synthesis and reactions of partially reduced biisoquinolines

被引：43

作者：

Elliott, MC ^{[1
]}

Williams, E ^{[1
]}

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2003年 / 1卷 / 17期

关键词：

D O I：

10.1039/b306159k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An improved synthesis of the 1,1', 2,2', 3,3', 4,4'-octahydro-1,1'-biisoquinoline ring system is described. The reactivity of this system has been investigated, including the unusually high basicity of the parent compound and its N,N'-dimethyl derivative. The resolution of the parent compound has been achieved for the first time, along with the development of a straightforward method for assaying its enantiomeric purity.

引用

页码：3038 / 3047

页数：10

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