Conjugate additions of nitroalkanes to electron-poor alkenes: Recent results

被引：518

作者：

Ballini, R ^{[1
]}

Bosica, G ^{[1
]}

Fiorini, D ^{[1
]}

Palmieri, A ^{[1
]}

Petrini, M ^{[1
]}

机构：

[1] Univ Camerino, Dipartimento Sci Chim, I-62032 Camerino, Italy

来源：

CHEMICAL REVIEWS | 2005年 / 105卷 / 03期

关键词：

D O I：

10.1021/cr040602r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nitroalkanes are a valuable source of stabilized carbanions because the high electron-withdrawing power of the nitro group provides an outstanding enhancement of the hydrogen acidity at the α-position. This review covers the utilization of nitroalkanes as nucleophiles in conjugate additions with electron-poor alkenes, as well as the new procedures and related applications appearing in the literature after 1990. Focus is on asymmetric additions carried out using optically active alkenes or with the aid of chiral catalysts.

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页码：933 / 971

页数：39

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