Mesoporous Metal-Organic Frameworks with Size-tunable Cages: Selective CO2 Uptake, Encapsulation of Ln3+ Cations for Luminescence, and Column-Chromatographic Dye Separation

被引：318

作者：

Lan, Ya-Qian ^{[1
,2
]}

Jiang, Hai-Long ^{[1
]}

Li, Shun-Li ^{[2
]}

Xu, Qiang ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Osaka 5638577, Japan

[2] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China

来源：

ADVANCED MATERIALS | 2011年 / 23卷 / 43期

关键词：

CARBON-DIOXIDE; HYDROGEN STORAGE; SURFACE-AREA; PORE-SIZE; ADSORPTION; CATALYSIS; CAPTURE; METHANE; TETRACARBOXYLATE; POROSITY;

D O I：

10.1002/adma.201102880

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three mesoporous metal-organic frameworks (MOFs) with rare corundum-type topology and size-tailored cages are constructed by length-extendable tetratopic ligands. All the MOFs show selective CO 2 uptake over N 2 and their CO 2 uptake capabilities are discriminated with different cage sizes. The MOFs can serve as hosts for encapsulating extra-framework lanthanide cations, and be applicable in column-chromatographic separation for large dye molecules. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5015 / 5020

页数：6

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