2-(2-Methoxyphenyl)-1,3-dimethyl-1H-benzoimidazol-3-ium Iodide as a New Air-Stable n-Type Dopant for Vacuum-Processed Organic Semiconductor Thin Films

被引：138

作者：

Wei, Peng ^{[1
]}

Menke, Torben ^{[2
]}

Naab, Benjamin D. ^{[1
]}

Leo, Karl ^{[2
]}

Riede, Moritz ^{[2
]}

Bao, Zhenan ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem Engn, Stanford, CA 94305 USA

[2] Tech Univ Dresden, Inst Angew Photophys, D-01069 Dresden, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 09期

关键词：

LIGHT-EMITTING-DIODES; ELECTRONIC MATERIALS; TRANSPORT MATERIAL; PYRONIN-B; CONDUCTIVITY; DEVICES; PHTHALOCYANINE; PHOTOEMISSION; ENHANCEMENT; DIANHYDRIDE;

D O I：

10.1021/ja211382x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2-(2-Methoxyphenyl)-1,3-dimethyl-1H-benzoimidazol-3-ium iodide (o-MeO-DMBI-I) was synthesized and employed as a strong n-type dopant for fullerene C-60, a well-known n-channel semiconductor. The coevaporated thin films showed a maximum conductivity of 5.5 S/cm at a doping concentration of 8.0 wt% (14 mol %), which is the highest value reported to date for molecular n-type conductors, o-MeO-DMBI-I can be stored and handled in air for extended periods without degradation and is thus promising for various organic electronic devices.

引用

收藏

页码：3999 / 4002

页数：4

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