Group 12 and heavier Group 13 alkali metal 'ate complexes

被引：67

作者：

Linton, DJ ^{[1
]}

Schooler, P ^{[1
]}

Wheatley, AEH ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

COORDINATION CHEMISTRY REVIEWS | 2001年 / 223卷

关键词：

alkali metal; 'ate complex; Group; 12; 13; solid-state structure;

D O I：

10.1016/S0010-8545(01)00379-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Heterobimetallic complexes in which a Group I metal centre counteracts the negative charge placed on a Group 12 or higher Group 13 metal have been known for some years. Their usefulness in chemical transformations is discussed in the context of the regiospecificity with which they effect reaction and the manner in which it differs to that resulting from the use of homometallic alkali metal reagents. Their structural properties are reported both in solution and in the solid state. Theoretical studies are presented where appropriate. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：53 / 115

页数：63

共 478 条

[1]

ADEL J, 1988, Z NATURFORSCH B, V43, P1094

[2] THE CONJUGATE ADDITION OF A SILYL GROUP TO ENONES AND ITS REMOVAL WITH COPPER(II) BROMIDE - A PROTECTING GROUP FOR THE ALPHA-BETA-UNSATURATION OF ALPHA-BETA-UNSATURATED KETONES [J].

AGER, DJ ;

FLEMING, I ;

PATEL, SK .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1981, (09) :2520-2526

[3] Reactions of the alkyltrihydroaluminate [Li(thf)2{AlH3[C(SiMe3)3]}]2.: Crystal structures of [Li(tmen)2][AlH3{C(SiMe3)3}], [AlBr2-{C(SiMe3)3}]•thf, [AlI2{C(SiMe3)3}]•thf, [Li(thf)2(μ-NHPh)2-{AlH[C(SiMe3)3]}] and {Li(thf)4][Al(NHPh)3{C(SiMe3)3}] [J].

Al-Juaid, SS ;

Eaborn, C ;

Gorrell, IB ;

Hawkes, SA ;

Hitchcock, PB ;

Smith, JD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (14) :2411-2415

[4]

Albrecht M, 1999, CHEM-EUR J, V5, P48, DOI 10.1002/(SICI)1521-3765(19990104)5:1<48::AID-CHEM48>3.3.CO

[5]

2-Z

[6] STRUCTURE OF COMPOUNDS CONTAINING LINEAR AND TETRAHEDRAL SILICON-MERCURY BONDS, A UNIQUELY CAGED LITHIUM ION [J].

ALBRIGHT, MJ ;

SCHAAF, TF ;

BUTLER, WM ;

HOVLAND, AK ;

GLICK, MD ;

OLIVER, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (21) :6261-6262

[7] THE PREPARATION AND CRYSTAL-STRUCTURES OF THE STERICALLY HINDERED LITHIUM ALKYLCHLOROCADMATE [LI(TETRAHYDROFURAN)4][LI(TETRAHYDROFURAN)2(MU-CL)4(CDC(SIME3)3)2].TETRAHYDROFURAN, THE ALKYCADMIUM HALIDES [(CD[C(SIME3)3]CL)4] AND [(CD[C(SIME2PH)3]BR)2], AND THE HYDRATE [(CD[C(SIME2PH)3]BR(H2O))]2.(TETRAHYDROFURAN- [J].

ALJUAID, SS ;

BUTTRUS, NH ;

EABORN, C ;

HITCHCOCK, PB ;

SMITH, JD ;

TAVAKKOLI, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (20) :1389-1391

[8] Build-up of an Al4P6Li4 cage from an Al4N4 cubane: Synthesis and structure of [Li(OC4H8)](4)[{(AlMe)[mu-P(C6H11)]}(2){mu-P(C6H11)}](2)center dot C(6)H(5)Me [J].

Allan, RE ;

Beswick, MA ;

Raithby, PR ;

Steiner, A ;

Wright, DS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (22) :4153-4154

[9] CRYSTAL STRUCTURE OF KF.2AI(C2H5)3 COMPLEX [J].

ALLEGRA, G ;

PEREGO, G .

ACTA CRYSTALLOGRAPHICA, 1963, 16 (03) :185-&

[10]

AMMA EL, 1983, AM CRYST ASS ABSTR P, V186, P39

← 1 2 3 4 5 6 7 8 9 10 →