Catalysis of the electrochemical H2 evolution by di-iron sub-site models

被引：248

作者：

Capon, JF ^{[1
]}

Gloaguen, F ^{[1
]}

Schollhammer, P ^{[1
]}

Talarmin, J ^{[1
]}

机构：

[1] Univ Bretagne Occidentale, CNRS, UMR 6521, UFR Sci & Tech, F-93837 Brest, France

来源：

COORDINATION CHEMISTRY REVIEWS | 2005年 / 249卷 / 15-16期

基金：

英国工程与自然科学研究理事会;

关键词：

hydrogenase; electrocatalysis; proton reduction; di-iron sub-site models; biomimetic catalysts; bioorganometallic chemistry;

D O I：

10.1016/j.ccr.2004.11.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A short non-exhaustive overview of hexacarbonyl dithiolate di-iron species and of their substituted derivatives relevant to the chemistry of the di-iron sub-site of the hydrogenase enzymes is presented. Although few detailed electrochemical studies have been reported until now, we discuss the use of di-iron organometallic species as catalysts for the electrochemical reduction of protons. Finally, we propose targets for the synthesis of more efficient biomimetic catalysts. (c) 2004 Elsevier B.V. All rights reserved.

引用

页码：1664 / 1676

页数：13

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