Mechanistic Insight into the Reduction of Tertiary Phosphine Oxides by Ti(OiPr)4/TMDS

被引：84

作者：

Petit, Christelle ^{[2
]}

Favre-Reguillon, Alain ^{[1
]}

Albela, Belen ^{[3
]}

Bonneviot, Laurent ^{[3
]}

Mignani, Gerard ^{[4
]}

Lemaire, Marc ^{[2
]}

机构：

[1] Conservatoire Natl Arts & Metiers, Lab Transformat Chim & Pharmaceut, UMR 7084, F-75003 Paris, France

[2] Univ Lyon 1, Lab Catalyse & Synth Organ, ICBMS, UMR 5246, F-69100 Villeurbanne, France

[3] Ecole Normale Super Lyon, Chim Lab, Grp Mat Hybrides, F-69364 Lyon 7, France

[4] Lyon Res Ctr, F-69192 St Fons, France

来源：

ORGANOMETALLICS | 2009年 / 28卷 / 22期

关键词：

X-RAY; POLYMETHYLHYDROSILOXANE PMHS; TITANIUM; HYDROSILYLATION; ALKOXIDES; CONVERSION; ALCOHOLS; KETONES; POLYMERIZATION; DERIVATIVES;

D O I：

10.1021/om900747b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reduction mechanism of tertiary phosphine oxides by Ti(OiPr)(4)/hydrosiloxane was studied. Strong improvement was achieved using a drying agent. ESR spectra of the reaction mixture give evidence for a single electronic transfer (SET) mechanism.

引用

页码：6379 / 6382

页数：4

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