Anomalous reactions of the diamine Me2NCH2NMe2 with nickel(II) and cobalt(II)

被引：11

作者：

Hitchcock, PB ^{[1
]}

Handley, DA ^{[1
]}

Lee, TH ^{[1
]}

Leigh, GJ ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 24期

关键词：

D O I：

10.1039/b207818j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The diamine Me2NCH2NMe2 (tmmn) is capable of forming simple adducts with most metal(II) ions of the first transition series, but with nickel and cobalt a variety of additional products can be obtained from its reaction with the dihalides. The diamine may be monodentate or bidentate, it may (formally) lose a hydride to generate a cation, and each N-C bond may break, generating new products containing additional methyl groups or the ions (Me2NH2)(+) or (Me2N=CH2)(+).

引用

页码：4720 / 4725

页数：6

共 18 条

[1] PREPARATION, STRUCTURE AND VIBRATIONAL-SPECTRUM OF THE DIMETHYLMETHYLENIMINIUM ION, INCLUDING THE ROLE OF CATIONIC POLYMERS IN ITS FORMATION [J].

CLARK, GR ;

SHAW, GL ;

SURMAN, PWJ ;

TAYLOR, MJ ;

STEELE, D .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1994, 90 (20) :3139-3144

[2] Linear tricobalt compounds with Di(2-pyridyl)amide (dpa) ligands:: Temperature dependence of the structural and magnetic properties of symmetrical and unsymmetrical forms of Co3(dpa)4Cl2 in the solid state [J].

Clérac, R ;

Cotton, FA ;

Daniels, LM ;

Dunbar, KR ;

Kirschbaum, K ;

Murillo, CA ;

Pinkerton, AA ;

Schultz, AJ ;

Wang, XP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (26) :6226-6236

[3] Can crystal structure determine molecular structure?: For Co3(dpa)4Cl2, yes [J].

Cotton, FA ;

Murillo, CA ;

Wang, XP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (19) :3327-3328

[4] The synthesis of triangulo-trimetal complexes containing both iron(II) and vanadium(II) [J].

Evans, DJ ;

Hitchcock, PB ;

Leigh, GJ ;

Nicholson, BK ;

Niedwieski, AC ;

Nunes, FS ;

Soares, JF .

INORGANICA CHIMICA ACTA, 2001, 319 (1-2) :147-158

[5] ABSOLUTE-CONFIGURATION OF BIOLOGICAL TETRAHYDROFOLATES - CRYSTALLOGRAPHIC DETERMINATION [J].

FONTECILLACAMPS, JC ;

BUGG, CE ;

TEMPLE, C ;

ROSE, JD ;

MONTGOMERY, JA ;

KISLIUK, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (20) :6114-6115

[6] Triangulo-pentahalotrimetal complexes of nickel(II) and cobalt(II) with N,N,N′,N′,N-tetrametbylethane-1,2-diamine and related compounds [J].

Handley, DA ;

Hitchcock, PB ;

Leigh, GJ .

INORGANICA CHIMICA ACTA, 2001, 314 (1-2) :1-13

[7] Complexes of metal(II) halides of the first transition series with N,N,N′,N′-tetramethylmethane-diamine, -ethane-1,2-diamine and -propane-1,3-diamine [J].

Handley, DA ;

Hitchcock, PB ;

Lee, TH ;

Leigh, GJ .

INORGANICA CHIMICA ACTA, 2001, 314 (1-2) :14-21

[8] Unique chains of alternating octahedral and tetrahedral cobalt(II) sites:: crystal structures of the novel chloro-bridged complexes [Co4(μ-Cl)6Cl2(thf)4(MeOH)2]n and [{Co4(μ-Cl)6Cl2(thf)4(H2O)2}•2THF]n [J].

Hierso, JC ;

Ellis, DD ;

Spek, AL ;

Bouwman, E ;

Reedijk, J .

CHEMICAL COMMUNICATIONS, 2000, (15) :1359-1360

[9] New compounds containing the triangulo-trichlorotrivanadium(II) moiety [J].

Hitchcock, PB ;

Hughes, DL ;

Larkworthy, LF ;

Leigh, GJ ;

Marmion, CJ ;

Sanders, JR ;

Smith, GW ;

deSouza, JS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (07) :1127-1135

[10]

HITCHCOCK PB, UNPUB

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