Solute diffusion in poly(vinyl alcohol) poly(acrylic acid) composite membranes prepared by freezing/thawing techniques

被引:43
作者
Hickey, AS [1 ]
Peppas, NA [1 ]
机构
[1] PURDUE UNIV,SCH CHEM ENGN,POLYMER SCI & ENGN LABS,W LAFAYETTE,IN 47907
关键词
poly(vinyl alcohol); poly(acrylic acid); freezing/thawing;
D O I
10.1016/S0032-3861(97)00163-8
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Composite membranes of poly(vinyl alcohol) and poly(acrylic acid) were prepared by freezing and thawing of aqueous solutions of the two components. The ensuing hydrogels and membranes exhibited crystallinity of up to 13.50% (on a swollen basis) due to crystallization of the poly(vinyl alcohol). The membranes prepared under these conditions exhibited size exclusion characteristics. Theophylline and FITC-dextran transport were investigated and the solute diffusion coefficients were correlated with the mesh size of the membranes. Copyright (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:5931 / 5936
页数:6
相关论文
共 65 条
[31]   SOLUTE DIFFUSION IN SWOLLEN MEMBRANES III. NON-EQUILIBRIUM THERMODYNAMIC ASPECTS OF SOLUTE DIFFUSION IN POLYMER NETWORK MEMBRANES [J].
Meadows, David L. ;
Peppas, Nikolaos A. .
CHEMICAL ENGINEERING COMMUNICATIONS, 1984, 31 (1-6) :101-119
[32]   MEMBRANE-POTENTIAL AND SALT PERMEABILITY OF CATIONIC POLY(VINYL ALCOHOL) MEMBRANES [J].
NAKANISHI, T ;
SEIKE, T ;
AKIYAMA, T ;
SATOH, M ;
KOMIYAMA, J .
JOURNAL OF MEMBRANE SCIENCE, 1989, 47 (1-2) :67-78
[33]   PERVAPORATION OF ALCOHOL TOLUENE MIXTURES THROUGH POLYMER BLEND MEMBRANES OF POLY(ACRYLIC ACID) AND POLY(VINYL ALCOHOL) [J].
PARK, HC ;
MEERTENS, RM ;
MULDER, MHV ;
SMOLDERS, CA .
JOURNAL OF MEMBRANE SCIENCE, 1994, 90 (03) :265-274
[34]   PRESSURE-INDUCED DIFFUSION OF ORGANIC LIQUIDS THROUGH HIGHLY SWOLLEN POLYMER MEMBRANES [J].
PAUL, DR ;
KEBRALIM.OM .
JOURNAL OF APPLIED POLYMER SCIENCE, 1970, 14 (09) :2201-&
[35]   REINFORCED UNCROSSLINKED POLY (VINYL ALCOHOL) GELS PRODUCED BY CYCLIC FREEZING-THAWING PROCESSES - A SHORT REVIEW [J].
PEPPAS, NA ;
STAUFFER, SR .
JOURNAL OF CONTROLLED RELEASE, 1991, 16 (03) :305-310
[36]   CROSSLINKED POLYVINYL-ALCOHOL) HYDROGELS AS SWOLLEN ELASTIC NETWORKS [J].
PEPPAS, NA ;
MERRILL, EW .
JOURNAL OF APPLIED POLYMER SCIENCE, 1977, 21 (07) :1763-1770
[37]  
Peppas NA., 1986, HYDROGELS MED PHARM, P27
[38]  
PEPPAS NA, 1977, POLYM PREP AM CHEM S, V18, P794
[39]  
PETER S, 1981, ACS SYM SER, V154, P281
[40]   SOLUTE DIFFUSION IN SWOLLEN MEMBRANES .2. INFLUENCE OF CROSSLINKING ON DIFFUSIVE PROPERTIES [J].
REINHART, CT ;
PEPPAS, NA .
JOURNAL OF MEMBRANE SCIENCE, 1984, 18 (MAR) :227-239