A Convenient and General Iron-Catalyzed Reduction of Amides to Amines

被引：244

作者：

Zhou, Shaolin ^{[1
]}

Junge, Kathrin ^{[1
]}

Addis, Daniele ^{[1
]}

Das, Shoubhik ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 50期

关键词：

amides; amines; homogeneous catalysis; iron; reduction; TERTIARY-AMINES; SELF-ENCAPSULATION; SILANE REDUCTION; HYDROSILYLATION; EFFICIENT; KETONES; HYDROSILANES; COMPLEXES; POLYMETHYLHYDROSILOXANE; HYDROGENATION;

D O I：

10.1002/anie.200904677

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

While the iron is hot: The first general and efficient iron-catalyzed reduction of secondary and tertiary amides into amines using polymethylhydrosiloxane (PMHS) has been developed (see scheme). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9507 / 9510

页数：4

共 41 条

[1]

[Anonymous], 2009, ANGEW CHEM

[2] Iron-catalyzed reactions in organic synthesis [J].

Bolm, C ;

Legros, J ;

Le Paih, J ;

Zani, L .

CHEMICAL REVIEWS, 2004, 104 (12) :6217-6254

[3] Reactions of hydrosilanes with transition-metal complexes: Formation of stable transition-metal silyl compounds [J].

Corey, JY ;

Braddock-Wilking, J .

CHEMICAL REVIEWS, 1999, 99 (01) :175-292

[4] Iron-catalysed carbon-heteroatom and heteroatom-heteroatom bond forming processes [J].

Correa, Arkaitz ;

Mancheno, Olga Garcia ;

Bolm, Carsten .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (06) :1108-1117

[5] Iron-Catalyzed Carbonylation: Selective and Efficient Synthesis of Succinimides [J].

Driller, Katrin Marie ;

Klein, Holger ;

Jackstell, Ralf ;

Beller, Matthias .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (33) :6041-6044

[6]

Enthaler S., 2008, Angew. Chem, V120, P3363

[7] Sustainable metal catalysis with iron: From rust to a rising star? [J].

Enthaler, Stephan ;

Junge, Kathrin ;

Beller, Matthias .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (18) :3317-3321

[8] An environmentally benign process for the hydrogenation of ketones with homogeneous iron catalysts [J].

Enthaler, Stephan ;

Hagemann, Bernhard ;

Erre, Giulia ;

Junge, Kathrin ;

Beller, Matthias .

CHEMISTRY-AN ASIAN JOURNAL, 2006, 1 (04) :598-604

[9] Biomimetic transfer hydrogenation of ketones with iron porphyrin catalysts [J].

Enthaler, Stephan ;

Erre, Giulia ;

Tse, Man Kin ;

Junge, Kathrin ;

Beller, Matthias .

TETRAHEDRON LETTERS, 2006, 47 (46) :8095-8099

[10] Reduction of amides with silanes catalyzed by MoO2Cl2 [J].

Fernandes, Ana C. ;

Romao, Carlos C. .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 272 (1-2) :60-63

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