Hypervalent iodine(III) reagents in organic synthesis

被引：353

作者：

Zhdankin, Viktor V. ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem & Biochem, Duluth, MN 55812 USA

来源：

ARKIVOC | 2009年

基金：

美国国家科学基金会;

关键词：

Hypervalent iodine; oxidation; (difluoroiodo)benzene; (dichloroiodo)benzene; iodosylbenzene; (diacetoxyiodo)benzene; hydroxy(tosyloxy)]iodobenzene; catalysis; recyclable reagents; M-CHLOROPERBENZOIC ACID; ONE-POT SYNTHESIS; ANOMERIC ALKOXYL RADICALS; IN-SITU GENERATION; POLYVALENT ORGANOIODINE COMPOUNDS; HIGHLY SELECTIVE OXIDATION; DIRECT ALPHA-HYDROXYLATION; ASYMMETRIC TOTAL SYNTHESES; P-IODOTOLUENE DIFLUORIDE; FLUOROUS ALKYL IODIDES;

D O I：

10.3998/ark.5550190.0010.101

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review summarizes the chemistry of hypervalent iodine (III) compounds with emphasis of their synthetic applications. The preparation and reactions of (difluoroiodo)arenes, (dichloroiodo)arenes, iodosylarenes, [bis (acyloxy)iodo] arenes, and aryliodine (III) organosulfonates are overviewed. Application of these reagents allows mild and highly selective oxidative transformations in a facile and environmentally friendly manner. Some of these useful transformations can be carried out using organoiodine (III) compounds as catalysts or recyclable reagents.

引用

页码：1 / 62

页数：62

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