A novel N-alkylation of amines by alkyl halides on mixed oxides at room temperature

被引：34

作者：

Gawande, Manoj B. ^{[1
]}

Deshpande, Sameer S. ^{[1
]}

Satam, Jitendra R. ^{[1
]}

Jayaram, Radha V. ^{[1
]}

机构：

[1] Univ Bombay, Inst Chem Technol, Dept Chem, Bombay 400019, Maharashtra, India

来源：

CATALYSIS COMMUNICATIONS | 2007年 / 8卷 / 03期

关键词：

N-alkylation; mixed oxides; tertiary amines; liquid phase reaction; room temperature (30 degrees C);

D O I：

10.1016/j.catcom.2006.08.011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Selective liquid phase N-alkylation of amines by alkyl halides using Al2O3-OK as a catalyst in the presence of acetonitrile at room temperature (30 degrees C) is described. The Al2O3-OK catalyst was characterized by XRD, SEM-EDXS, elemental analysis, particle size analysis, BET surface area, pore size and average pore diameter. The catalyst used for this synthetically useful transformation showed a considerable level of reusability as well as good activity. (c) 2006 Published by Elsevier B.V.

引用

页码：576 / 582

页数：7

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