A resourceful new strategy in organic synthesis: Tandem and stepwise metathesis/non-metathesis catalytic processes

被引：91

作者：

Dragutan, Valerian ^{[1
]}

Dragutan, Ileana ^{[1
]}

机构：

[1] Romanian Acad, Inst Organ Chem, Bucharest 060023, Romania

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2006年 / 691卷 / 24-25期

关键词：

tandem; catalysis; metathesis; metal-alkylidenes; transition metals; non-metathetical processes;

D O I：

10.1016/j.jorganchem.2006.08.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Highlighting the impressive potential of tandem and stepwise metathesis/non-metathesis reactions in synthesis, the present review extends the scope of the newly gained renown of metathesis as a progressive policy for advanced, elegant and economical organic synthesis. Background is provided for the most encountered to date applications where fundamental non-metathetical synthetic transformations (hydrogenation, oxidation, isomerization, allylation, cyclopropanation, etc.) and a variety of name reactions (Diels-Alder, Claisen, Heck, Ugi, Pauson-Khand, Kharasch addition, etc.) are occurring in tandem, as concurrent or sequential processes, with every known type of metathetical reactions catalyzed by ruthenium or molybdenum complexes. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：5129 / 5147

页数：19

共 172 条

[1] Two birds with one metallic stone: Single-pot catalysis of fundamentally different transformations [J].

Ajamian, A ;

Gleason, JL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (29) :3754-3760

[2] Ruthenium-catalyzed chemoselective N-allyl cleavage: Novel Grubbs carbene mediated deprotection of allylic amines [J].

Alcaide, B ;

Almendros, P ;

Alonso, JM .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (23) :5793-5799

[3] Non-metathetic behavior patterns of Grubbs' carbene [J].

Alcaide, B ;

Almendros, P .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (06) :1259-1262

[4] Synthesis of substituted 1,2-dihydroquinolines and quinolines using ene-ene metathesis and ene-enol ether metathesis [J].

Arisawa, M ;

Theeraladanon, C ;

Nishida, A ;

Nakagawa, M .

TETRAHEDRON LETTERS, 2001, 42 (45) :8029-8033

[5] Application of tandem Ugi reaction/ring-closing metathesis in multicomponent synthesis of unsaturated nine-membered lactams [J].

Banfi, L ;

Basso, A ;

Guanti, G ;

Riva, R .

TETRAHEDRON LETTERS, 2003, 44 (41) :7655-7658

[6]

Banti D, 2002, ADV SYNTH CATAL, V344, P694, DOI 10.1002/1615-4169(200208)344:6/7<694::AID-ADSC694>3.0.CO

[7]

2-X

[8] Tandem Ireland-Claisen rearrangement ring-closing alkene metathesis in the construction of bicyclic β-lactam carboxylic esters [J].

Barrett, AGM ;

Ahmed, M ;

Baker, SP ;

Baugh, SPD ;

Braddock, DC ;

Procopiou, PA ;

White, AJP ;

Williams, DJ .

JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (12) :3716-3721

[9] Primary products and mechanistic considerations in alkane metathesis [J].

Basset, JM ;

Copéret, C ;

Lefort, L ;

Maunders, BM ;

Maury, O ;

Le Roux, E ;

Saggio, G ;

Soignier, S ;

Soulivong, D ;

Sunley, GJ ;

Taoufik, M ;

Thivolle-Cazat, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (24) :8604-8605

[10] Sequential catalysis: A metathesis/dihydroxylation sequence [J].

Beligny, S ;

Eibauer, S ;

Maechling, S ;

Blechert, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (12) :1900-1903

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