Functionalised 2,2′-bipyridine ligands for the preparation of metallostars;: X-ray structures of free ligands and preparation of copper(I) and silver(I) complexes

被引：35

作者：

Constable, EC ^{[1
]}

Housecroft, CE ^{[1
]}

Neuburger, M ^{[1
]}

Poleschak, I ^{[1
]}

Zehnder, M ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

POLYHEDRON | 2003年 / 22卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

copper; silver; ruthenium; 2,2 '-bipyridine; metallostar; X-ray;

D O I：

10.1016/S0277-5387(02)01310-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

2,2-Bipyridine ligands bearing functionalised aryl substituents have been prepared with the aim of subsequent functionalisation and the preparation of multinuclear metallostars. The key intermediates are compounds containing 4-methoxyphenyl substituents which may be converted to 4-hydroxyphenyl substituted ligands. Copper(I) and silver(I) complexes of 4,4'-di(methoxyphenyl)-6,6'-dimethyl-2,2'-bipyridine have been prepared and structurally characterised as have the ligands 4,4'-di(methoxypheny1)-6,6'-dimethyl-2,2'-bipyridine and 4,4'-di(methoxyphenyl)-2,2'-bipyridine. (C) 2002 Published by Elsevier Science Ltd.

引用

页码：93 / 108

页数：16

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