Synthesis of poly-ferrocene heterocycles by cycloaddition of mono- or bis(ferrocenecarbonyl)acetylenes and bis[1,2]dithiolo[1,4]thiazinethiones

被引:30
作者
Barriga, S
Marcos, CF
Riant, O
Torroba, T [1 ]
机构
[1] Univ Burgos, Fac Ciencias, Dept Quim, Burgos 09001, Spain
[2] Univ Extremadura, Fac Vet, Dept Quim Organ, Caceres 10071, Spain
[3] Univ Catholique Louvain, Dept Chim, B-1348 Louvain, Belgium
关键词
ferrocene; heterocycle; dithiole; thiazine; extended TTF; cyclic voltammetry;
D O I
10.1016/S0040-4020(02)01295-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Cycloaddition of a bis[1,2]dithiolo[1,4]thiazine ketothione and mono- or bis(ferrocenecarbonyl)acetylenes under catalysis by scandium triflate gave mono- and bis-ferrocenecarbonyl-1,3-dithiolylidene[1,2]dithiolo[1,4]thiazines. Cycloaddition of a bis-dithiolothiazine dithione and bis-ferrocenylbutynedione gave 3,5-di(bis-ferrocenecarbonyl-1,3-dithiolylidene)[1,4]thiazine, a structure related to extended tetrathiafulvalenes. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:9785 / 9792
页数:8
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