Synthesis of poly-ferrocene heterocycles by cycloaddition of mono- or bis(ferrocenecarbonyl)acetylenes and bis[1,2]dithiolo[1,4]thiazinethiones

被引：30

作者：

Barriga, S

Marcos, CF

Riant, O

Torroba, T ^{[1
]}

机构：

[1] Univ Burgos, Fac Ciencias, Dept Quim, Burgos 09001, Spain

[2] Univ Extremadura, Fac Vet, Dept Quim Organ, Caceres 10071, Spain

[3] Univ Catholique Louvain, Dept Chim, B-1348 Louvain, Belgium

来源：

TETRAHEDRON | 2002年 / 58卷 / 49期

关键词：

ferrocene; heterocycle; dithiole; thiazine; extended TTF; cyclic voltammetry;

D O I：

10.1016/S0040-4020(02)01295-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cycloaddition of a bis[1,2]dithiolo[1,4]thiazine ketothione and mono- or bis(ferrocenecarbonyl)acetylenes under catalysis by scandium triflate gave mono- and bis-ferrocenecarbonyl-1,3-dithiolylidene[1,2]dithiolo[1,4]thiazines. Cycloaddition of a bis-dithiolothiazine dithione and bis-ferrocenylbutynedione gave 3,5-di(bis-ferrocenecarbonyl-1,3-dithiolylidene)[1,4]thiazine, a structure related to extended tetrathiafulvalenes. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：9785 / 9792

页数：8

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