Tetrathiafulvalene (TTF) derivatives: key building-blocks for switchable processes

被引:524
作者
Canevet, David [2 ]
Salle, Marc [2 ]
Zhang, Guanxin [1 ]
Zhang, Deqing [1 ]
Zhu, Daoben [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Organ Solids Lab, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[2] Univ Angers, CNRS, CIMA UMR 6200, UFR Sci, F-49045 Angers, France
关键词
INTRAMOLECULAR ELECTRON-TRANSFER; REDOX-ACTIVE LIGANDS; SELF-ASSEMBLED MONOLAYERS; CHARGE-TRANSFER; CROWN-ETHER; METAL-ION; ANTHRACENE DYAD; SUBSTITUTED TETRATHIAFULVALENE; ANION RECOGNITION; INCORPORATING TETRATHIAFULVALENE;
D O I
10.1039/b818607n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Besides a traditional use for the development of organic conducting materials, the tetrathiafulvalene (TTF) unit and its derivatives have recently appeared as key constituents for new applications, exploiting remarkable redox properties: a high p-donating ability and occurrence of three stable redox states. Indeed, in very recent years, an impressive variety of switchable TTF-based molecular and supramolecular (multifunctional) architectures have been designed and synthesized. In this feature article, we discuss recent developments of TTF-based molecular and supramolecular systems in this respect, including molecular sensors, redox. uorescent switches, multi-input systems for logic gates, electrochemically-driven conformational controls, molecular clips and tweezers, and redox-controlled gelation processes.
引用
收藏
页码:2245 / 2269
页数:25
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