Arene Ruthenium Cages: Boxes Full of Surprises

被引：204

作者：

Therrien, Bruno ^{[1
]}

机构：

[1] Univ Neuchatel, Inst Chem, CH-2009 Neuchatel, Switzerland

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 17期

关键词：

Arene ligands; Bioinorganic chemistry; Ruthenium; Self-assembly; Supramolecular chemistry; G-QUADRUPLEX DNA; PRISMATIC ALTITUDINAL ROTORS; SPIN-SPIN INTERACTION; MOLECULAR SQUARES; HALF-SANDWICH; STEPWISE FORMATION; BUILDING-BLOCKS; METALLO-PRISMS; BIOORGANOMETALLIC CHEMISTRY; ORGANOMETALLIC BOXES;

D O I：

10.1002/ejic.200900180

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Self-assembly of polypyridyl ligands with dinuclear arene ruthenium building blocks bridged by chlorido, oxalato or benzoquinonato ligands has allowed the construction of a wide range of cationic metalla complexes possessing different architectures and functionalities: (i) metalla-rectangles showing host-guest possibilities and allowing intramolecular template-controlled photochemical [2 + 2] dimerisation reactions; (ii) metalla-prisms allowing encapsulation of molecules and giving rise to potential drug delivery systems; (iii) metalla-boxes that can be used to stabilise the formation of G-quadruplex DNA. This microreview covers the synthetic and structural aspects of these metalla complexes, as well as their most promising applications, with a particular focus on their potential biological applications. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：2445 / 2453

页数：9

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