Engineering a Metal-Organic Framework Catalyst by Using Postsynthetic Modification

被引：207

作者：

Tanabe, Kristine K. ^{[1
]}

Cohen, Seth M. ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 40期

基金：

美国国家科学基金会;

关键词：

chelation; heterogeneous catalysis; metal-organic frameworks; postsynthetic modification; zinc; COVALENT MODIFICATION; FUNCTIONALIZATION; SIZE;

D O I：

10.1002/anie.200903433

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

MOF+PSM=Cat: A highly porous metal-organic framework (MOF) is metalated and transformed into an active, robust, reusable catalyst (Cat.) using postsynthetic modification (PSM). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7424 / 7427

页数：4

共 38 条

[1] Synthesis and Modification of a Functionalized 3D Open-Framework Structure with MIL-53 Topology [J].

Ahnfeldt, Tim ;

Gunzelmann, Daniel ;

Loiseau, Thierry ;

Hirsemann, Dunja ;

Senker, Juergen ;

Ferey, Gerard ;

Stock, Norbert .

INORGANIC CHEMISTRY, 2009, 48 (07) :3057-3064

[2] Postsynthetic Modification Switches an Achiral Framework to Catalytically Active Homochiral Metal-Organic Porous Materials [J].

Banerjee, Mainak ;

Das, Sunirban ;

Yoon, Minyoung ;

Choi, Hee Jung ;

Hyun, Myung Ho ;

Park, Se Min ;

Seo, Gon ;

Kim, Kimoon .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (22) :7524-+

[3]

BURROWS AD, 2008, ANGEW CHEM, V120, P8610

[4] Post-Synthetic Modification of Tagged Metal-Organic Frameworks [J].

Burrows, Andrew D. ;

Frost, Christopher G. ;

Mahon, Mary F. ;

Richardson, Christopher .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (44) :8482-8486

[5] Sulfur-tagged metal-organic frameworks and their post-synthetic oxidation [J].

Burrows, Andrew D. ;

Frost, Christopher G. ;

Mahon, Mary F. ;

Richardson, Christopher .

CHEMICAL COMMUNICATIONS, 2009, (28) :4218-4220

[6]

Cohen SM, 2001, CHEM-EUR J, V7, P272, DOI 10.1002/1521-3765(20010105)7:1<272::AID-CHEM272>3.3.CO

[7]

2-P

[8] Chemical modification of a bridging ligand inside a metal-organic framework while maintaining the 3D structure [J].

Costa, Jose Sanchez ;

Gamez, Patrick ;

Black, Cory A. ;

Roubeau, Olivier ;

Teat, Simon J. ;

Reedijk, Jan .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (10) :1551-1554

[9] Industrial applications of metal-organic frameworks [J].

Czaja, Alexander U. ;

Trukhan, Natalia ;

Mueller, Ulrich .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1284-1293

[10] Isoreticular Metalation of Metal-Organic Frameworks [J].

Doonan, Christian J. ;

Morris, William ;

Furukawa, Hiroyasu ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (27) :9492-+

← 1 2 3 4 →