Closed and Open Clamlike Structures Formed by Hydrogen-Bonded Pairs of Cyclotricatechylene Anions that Contain Cationic "Meat"

被引：42

作者：

Abrahams, Brendan F. ^{[1
]}

FitzGerald, Nicholas J. ^{[1
]}

Hudson, Timothy A. ^{[1
]}

Robson, Richard ^{[1
]}

Waters, Tom ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 17期

基金：

澳大利亚研究理事会;

关键词：

catechols; cation trapping; hydrogen bonding; inclusion compounds; supramolecular chemistry; CRYSTAL-STRUCTURES; CYCLOTRIVERATRYLENE; MOLECULES;

D O I：

10.1002/anie.200805789

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Clamming up: The hexaphenolic compound cyclotricatechylene, which has a bowl-shaped cavity, forms clamlike pairs that encapsulate cations (see picture). Variable hydrogen bonding allows two linked cyclotricatechylene clamshells to be in a closed arrangement when smaller cations such Rb+ or Cs +provide the clam meat, whereas larger cations such as NMe 4+ and NEt4+ cause the clam to be partially opened. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3129 / 3132

页数：4

共 24 条

[1]

Abrahams B. F., 2006, ANGEW CHEM, V118, P820

[2] Tetraanionic organoborate squares glued together by cations to generate nanotubular stacks [J].

Abrahams, BF ;

Price, DJ ;

Robson, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (05) :806-810

[3]

ABRAHAMS BF, 2007, ANGEW CHEM, V119, P8794

[4] Trianionic Organoborate Triangles [J].

Abrahams, Brendan F. ;

Boughton, Berin A. ;

Choy, Haozhen ;

Clarke, Oliver ;

Grannas, Martin J. ;

Price, David J. ;

Robson, Richard .

INORGANIC CHEMISTRY, 2008, 47 (21) :9797-9803

[5] An extensive class of solids full of holes large enough to enclose over 200 molecules of H2O [J].

Abrahams, Brendan F. ;

FitzGerald, Nicholas J. ;

Robson, Richard .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (45) :8640-8643

[6] CONDENSATION PRODUCTS OF PHENOLS AND KETONES .10. THE STRUCTURE OF DIANIN COMPOUND, A UNIQUE INCLUSION-FORMING SUBSTANCE [J].

BAKER, W ;

FLOYD, AJ ;

MCOMIE, JFW ;

POPE, G ;

WEAVING, AS ;

WILD, JH .

JOURNAL OF THE CHEMICAL SOCIETY, 1956, (JUL) :2010-2017

[7] CYCLOTRIVERATRYLENES AND CRYPTOPHANES [J].

COLLET, A .

TETRAHEDRON, 1987, 43 (24) :5725-5759

[8]

Collet A., 1996, COMPREHENSIVE SUPRAM, V6, P281

[9]

COTTON FA, 1988, ADV INORG CHEM, P39

[10] Models for the reactive states of homocuprates:: syntheses, structures and reactivities of [Cu2Li2Mes4] and Cu3LiMes4] [J].

Davies, Robert P. ;

Hornauer, Stefan ;

White, Andrew J. P. .

CHEMICAL COMMUNICATIONS, 2007, (03) :304-306

← 1 2 3 →