Metal-Bronsted Acid Cooperative Catalysis for Asymmetric Reductive Amination

被引:285
作者
Li, Chaoqun [1 ]
Villa-Marcos, Barbara [1 ]
Xiao, Jianliang [1 ]
机构
[1] Univ Liverpool, Liverpool Ctr Mat & Catalysis, Dept Chem, Liverpool L69 7ZD, Merseyside, England
基金
英国工程与自然科学研究理事会;
关键词
TRANSFER HYDROGENATION; ACYCLIC IMINES; KETONES; LIGANDS; COMPLEXES; CHEMISTRY; ALDEHYDES; AMINES;
D O I
10.1021/ja9021683
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Direct reductive amination of a wide range of ketones has been accomplished by the cooperative catalysis of an Ir(III)-diamine complex and a chiral phosphoric acid or its conjugate base.
引用
收藏
页码:6967 / +
页数:4
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