Non-linear effects in acyclic amino acid-catalyzed direct asymmetric aldol reactions

被引：25

作者：

Dziedzic, Pawel ^{[1
]}

Zou, Weibiao ^{[1
]}

Ibrahem, Ismail ^{[1
]}

Sunden, Henrik ^{[1
]}

Cordova, Armando ^{[1
]}

机构：

[1] Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 37期

关键词：

D O I：

10.1016/j.tetlet.2006.06.167

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Non-linear effects were observed in acyclic amino acid-catalyzed direct asymmetric intermolecular aldol reactions. The non-linear effects are due to the equilibrium solid-liquid phase behavior of amino acids. The results suggest that the phase behavior of amino acids linked to asymmetric catalysis may have implications to the evolution of homochirality. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：6657 / 6661

页数：5

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