Rhodium catalyzed reaction of internal alkynes with organoborons under CO atmosphere: a product tunable reaction

被引：27

作者：

Artok, Levent ^{[1
]}

Kus, Melih ^{[1
]}

Aksin-Artok, Oezge ^{[1
]}

Dege, Fatma Nurcan ^{[1
]}

Oezkilinc, Fatma Yelda ^{[1
]}

机构：

[1] Izmir Inst Technol, Fac Sci, Dept Chem, TR-35430 Izmir, Turkey

来源：

TETRAHEDRON | 2009年 / 65卷 / 45期

关键词：

Carbonylation; Rhodium catalysis; Organoborons; ARYLBORONIC ACIDS; CARBONYLATIVE CYCLIZATION; TERMINAL ALKYNES; ARYL IODIDES; ANNULATION; ARYLATION; EFFICIENT;

D O I：

10.1016/j.tet.2009.09.044

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkynes react with organoborons under a CO atmosphere in the presence of a rhodium(I) catalyst to afford mainly 5-aryl-2(5H)-furanones, alpha,beta-unsaturated ketones, and indanones. The product selectivity can be tuned by modifying the reaction conditions. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：9125 / 9133

页数：9

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