Directional synthesis of tin oxide@graphene nanocomposites via a one-step up-scalable wet-mechanochemical route for lithium ion batteries

被引：51

作者：

Li, Sheng ^{[1
]}

Wang, Yazhou ^{[1
]}

Lai, Chao ^{[1
]}

Qiu, Jingxia ^{[1
]}

Ling, Min ^{[1
]}

Martens, Wayde ^{[2
]}

Zhao, Huijun ^{[1
]}

Zhang, Shanqing ^{[1
]}

机构：

[1] Griffith Univ, Environm Futures Res Inst, Griffith Sch Environm, Ctr Clean Environm & Energy, Griffith, NSW 4222, Australia

[2] Queensland Univ Technol, Discipline Nanotechnol & Mol Sci, Brisbane, Qld 4001, Australia

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2014年 / 2卷 / 26期

关键词：

ANODE MATERIALS; CONTROLLED MORPHOLOGY; SNO2; NANOCRYSTALS; CARBON NANOTUBES; STORAGE CAPACITY; COMPOSITE; PERFORMANCE; NANOSHEETS; NANOPARTICLES; NANOMATERIALS;

D O I：

10.1039/c4ta01131g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Directional synthesis of SnO2@graphene nanocomposites via a one-step, low-cost, and up-scalable wet-mechanochemical method is achieved using graphene oxide and SnCl2 as precursors. The graphene oxides are reduced to graphene while the SnCl2 is oxidized to SnO2 nanoparticles that are in situ anchored onto the graphene sheets evenly and densely, resulting in uniform SnO2@graphene nanocomposites. The prepared nanocomposites possess excellent electrochemical performance and outstanding cycling in Li-ion batteries.

引用

收藏

页码：10211 / 10217

页数：7

相关论文

共 43 条

[1] Solvent-assisted mechanochemistry [J].

Bowmaker, Graham A. .

CHEMICAL COMMUNICATIONS, 2013, 49 (04) :334-348

[2] Mechanochemical preparation of co-crystals [J].

Braga, Dario ;

Maini, Lucia ;

Grepioni, Fabrizia .

CHEMICAL SOCIETY REVIEWS, 2013, 42 (18) :7638-7648

[3] SnO2-Based Nanomaterials: Synthesis and Application in Lithium-Ion Batteries [J].

Chen, Jun Song ;

Lou, Xiong Wen .

SMALL, 2013, 9 (11) :1877-1893

[4] One-step synthesis of SnO2-reduced graphene oxide-carbon nanotube composites via microwave assistance for lithium ion batteries [J].

Chen, Taiqiang ;

Pan, Likun ;

Liu, Xinjiuan ;

Yu, Kai ;

Sun, Zhuo .

RSC ADVANCES, 2012, 2 (31) :11719-11724

[5] In Situ Generation of Few-Layer Graphene Coatings on SnO2-SiC Core-Shell Nanoparticles for High-Performance Lithium-Ion Storage [J].

Chen, Zhongxue ;

Zhou, Min ;

Cao, Yuliang ;

Ai, Xinping ;

Yang, Hanxi ;

Liu, Jun .

ADVANCED ENERGY MATERIALS, 2012, 2 (01) :95-102

[6] SnO2 nanosheets grown on graphene sheets with enhanced lithium storage properties [J].

Ding, Shujiang ;

Luan, Deyan ;

Boey, Freddy Yin Chiang ;

Chen, Jun Song ;

Lou, Xiong Wen .

CHEMICAL COMMUNICATIONS, 2011, 47 (25) :7155-7157

[7] BASIC TIN(22) CHLORIDE [J].

DONALDSON, JD ;

SIMPSON, WB ;

MOSER, W .

JOURNAL OF THE CHEMICAL SOCIETY, 1963, (MAR) :1727-&

[8] Synthesis of tin (II or IV) oxide coated multiwall carbon nanotubes with controlled morphology [J].

Fang, Hai-Tao ;

Sun, Xue ;

Qian, Li-Hua ;

Wang, Da-Wei ;

Li, Feng ;

Chu, Yi ;

Wang, Fu-Ping ;

Cheng, Hui-Ming .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (15) :5790-5794

[9] The Li-Ion Rechargeable Battery: A Perspective [J].

Goodenough, John B. ;

Park, Kyu-Sung .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (04) :1167-1176

[10] Fabrication of superior-performance SnO2@C composites for lithium-ion anodes using tubular mesoporous carbon with thin carbon walls and high pore volume [J].

Han, Fei ;

Li, Wen-Cui ;

Li, Ming-Run ;

Lu, An-Hui .

JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (19) :9645-9651

← 1 2 3 4 5 →