Electrochemically induced addition reactions in the absence of solvent and supporting electrolyte

被引：23

作者：

Caruso, Tonino

Feroci, Marta

Inesi, Achille

Orsini, Monica

Scettri, Arrigo

Palombi, Laura

机构：

[1] Univ Salerno, Dipartimento Chim, I-84081 Baronissi, Italy

[2] Univ Roma La Sapienza, Dipartimento ICMMPM, I-00161 Rome, Italy

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2006年 / 348卷 / 14期

关键词：

electrogenerated enolates; electrosynthesis; Michael addition; nitroaldol reaction; solventless electrolysis;

D O I：

10.1002/adsc.200606082

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Solvent- and supporting electrolyte-free electrolysis in a two-compartment cell proved to be effective for the direct electroactivation of C-H acid-containing compounds vs. catalytic addition processes. Michael adducts (including quaternary carbon centres) and 2-nitroalkanols were obtained in very good yields and selectivity on application of a catalytic amount of electricity under galvanostatic conditions.

引用

收藏

页码：1942 / 1947

页数：6

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