Electrical resistivity in amorphous Si-Ln (Ln: Nd, Sm, Gd) alloy powders prepared by mechanical alloying

被引:10
作者
Ohba, N [1 ]
Arakawa, T [1 ]
机构
[1] KINKI UNIV KYUSHU,FAC ENGN,DEPT IND CHEM,IIZUKA,FUKUOKA 820,JAPAN
关键词
mechanical alloying; rare earth silicides; resistivity; amorphous;
D O I
10.1016/S0169-4332(97)00270-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Amorphous alloys Ln(1-x)Si(x) (Ln: Nd, Sm, Gd) were prepared by means of mechanical alloying in the concentration range 0.33 < x < 0.66. The crystallization behavior was investigated by DTA and XRD. The crystalline phases were observed for Ln(5)Si(3) and LnSi(2), except for a Si-Sm system. The resistivity changes of the crystallized samples obtained by cooling to room temperature exhibited classical metallic behavior. Moreover, at 77-298 K transformation points were observed, lying at 111-116 K for a Si-Nd system, at 93-97 K for a Si-Sm system and at 132-138 K for a Si-Gd system. (C) 1997 Elsevier Science B.V.
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页码:125 / 128
页数:4
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