The formation of cobalt silicide by the reaction of a Co layer with a Si substrate is known to be sensitive to the presence of oxygen contamination in the reaction region. A layer of Ti deposited on top of the Co is known to getter oxygen impurities. However, the presence of a Ti capping layer induces; two additional effects: firstly, the nucleation temperature of CoSi2 is increased by 60-80 degreesC. Secondly, the CoSi2 that is formed in the presence of a Ti capping layer has a preferential (2 2 0) and (4 0 0) orientation. A detailed study is presented on the influence of several processing parameters (annealing temperature, selective etching, layer thickness) oil the nucleation temperature and preferential orientation of CoSi2 in the Ti/Co/Si system. (C) 2003 Elsevier B.V. Ail rights reserved.