Novel expansion/shrinkage modulation of 2D layered MOF triggered by clathrate formation with CO2 molecules

被引：242

作者：

Kondo, Atsushi

Noguchi, Hiroshi

Ohnishi, Shunsuke

Kajiro, Hiroshi ^{[1
]}

Tohdoh, Aya

Hattori, Yoshiyuki

Xu, Wei-Chun

Tanaka, Hideki

Kanoh, Hirofumi

Kaneko, Katsumi

机构：

[1] Nippon Steel Corp Ltd, Futtsu, Chiba 2938511, Japan

[2] Chiba Univ, Grad Sch Sci & Technol, Chiba 2638522, Japan

[3] Inst Res & Innovat, Kashiwa, Chiba 2770861, Japan

来源：

NANO LETTERS | 2006年 / 6卷 / 11期

关键词：

D O I：

10.1021/nl062032b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystal-to-crystal transformation from a 3D interpenetrated-type MOF {[Cu(BF4)(2)(bpy)(H2O)(2)](bpy)}(1) to a 2D square-grid-type [Cu(BF4)(2)-(bpy)2](2)(bpy=4,4'-bipyridine) was observed. It was derived from dehydration and confirmed by in situ FT-IR, TG, and elemental analysis. Moreover, we elucidate the novel expansion/shrinkage dynamic modulation of 2 triggered by clathrate formation with gas molecules.

引用

页码：2581 / 2584

页数：4

共 46 条

[1] Alberti G, 1999, ANGEW CHEM INT EDIT, V38, P3351, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3351::AID-ANIE3351>3.0.CO
[2] 2-V
[3] EXPO:: a program for full powder pattern decomposition and crystal structure solution
Altomare, A
Burla, MC
Camalli, M
Carrozzini, B
Cascarano, GL
Giacovazzo, C
Guagliardi, A
Moliterni, AGG
Polidori, G
Rizzi, R
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 : 339 - 340
[4] Mineralomimetic sodalite- and muscovite-type coordination frameworks. Dynamic crystal-to-crystal interconversion processes sensitive to ion pair recognition
Barea, E
Navarro, JAR
Salas, JM
Masciocchi, N
Galli, S
Sironi, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (10) : 3014 - 3015
[5] BARRER RM, 1978, ZEOLITES CLAY MINERA, P290
[6] Biradha K, 2002, ANGEW CHEM INT EDIT, V41, P3395, DOI 10.1002/1521-3773(20020916)41:18<3395::AID-ANIE3395>3.0.CO
[7] 2-D
[8] Rectangular grid two-dimensional sheets of copper(II) bridged by both co-ordinated and hydrogen bonded 4,4'-bipyridine (4,4'-bipy) in [Cu(mu-4,4'-bipy)(H2O)(2)(FBF3)(2)]center dot 4,4'-bipy
Blake, AJ
Hill, SJ
Hubberstey, P
Li, WS
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (06): : 913 - 914
[9] Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47
Bourrelly, S
Llewellyn, PL
Serre, C
Millange, F
Loiseau, T
Férey, G
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (39) : 13519 - 13521
[10] A three-dimensional nanoporous flexible network of 'square-planar' copper(II) centres with an unusual topology
Carlucci, L
Cozzi, N
Ciani, G
Moret, M
Proserpio, DM
Rizzato, S
[J]. CHEMICAL COMMUNICATIONS, 2002, (13) : 1354 - 1355

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