Insertion into dihydrogen employing the nitrogen centre of a borylnitrene

被引：30

作者：

Bettinger, Holger F. ^{[1
,2
]}

Filthaus, Matthias ^{[1
]}

Neuhaus, Patrik ^{[1
]}

机构：

[1] Ruhr Univ Bochum, Lehrstuhl Organ Chem 2, D-44780 Bochum, Germany

[2] Univ Tubingen, Inst Organ Chem, D-72076 Tubingen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 16期

关键词：

FREE CATALYTIC-HYDROGENATION; HETEROLYTIC H-2 ACTIVATION; INFRARED-SPECTRUM; TRANSITION-METALS; LEWIS PAIR; COMPLEXES; CARBENE; MATRIX; REACTIVITY; METHANE;

D O I：

10.1039/b817270f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A borylnitrene, accessible from the corresponding azide by UV photolysis in a solid D(2) matrix at 3 K, inserts into D(2) upon visible light irradiation under cryogenic conditions.

引用

页码：2186 / 2188

页数：3

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