Selective reduction of CO2 to a methanol equivalent by B(C6F5)3-activated alkaline earth catalysis

被引：122

作者：

Anker, Mathew D. ^{[1
]}

Arrowsmith, Merle ^{[1
]}

Bellham, Peter ^{[1
]}

Hill, Michael S. ^{[1
]}

Kociok-Koehn, Gabriele ^{[1
]}

Liptrot, David J. ^{[1
]}

Mahon, Mary F. ^{[1
]}

Weetman, Catherine ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

CHEMICAL SCIENCE | 2014年 / 5卷 / 07期

基金：

英国工程与自然科学研究理事会;

关键词：

CARBON-DIOXIDE; HOMOGENEOUS HYDROGENATION; ORGANOMETALLIC COMPLEXES; FORMIC-ACID; CALCIUM; HYDROBORATION; BICARBONATES; CONVERSION;

D O I：

10.1039/c4sc00885e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of beta-diketiminato Mg and Ca amidoborane compounds with B(C6F5)(3) induces hydride elimination and formation of alkaline earth hydrido-tris(pentafluorophenyl) borate derivatives. Both species react with CO2 to provide formate complexes, one of which has been structurally characterised, and may be applied to the highly selective reductive hydroboration of CO2 with pinacolborane (HBpin) to provide the methanol equivalent, CH(3)OBpin.

引用

收藏

页码：2826 / 2830

页数：5

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