Ionic Liquid Electrolytes for Li-Air Batteries: Lithium Metal Cycling

被引：66

作者：

Grande, Lorenzo ^{[1
,2
]}

Paillard, Elie ^{[1
,2
]}

Kim, Guk-Tae ^{[1
,2
]}

Monaco, Simone ^{[3
]}

Passerini, Stefano ^{[1
,2
,4
]}

机构：

[1] Univ Munster, Inst Phys Chem, D-48149 Munster, Germany

[2] Univ Munster, Munster Electrochem Energy Technol MEET Battery, D-48149 Munster, Germany

[3] Alma Mater Studiorum Univ Bologna, Dipartimento Chim Giacomo Ciamician, I-40126 Bologna, Italy

[4] Karlsruhe Inst Technol, Helmholtz Inst Ulm, D-89081 Ulm, Germany

来源：

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES | 2014年 / 15卷 / 05期

关键词：

lithium air batteries; ionic liquids; lithium metal; electrolytes; Pyr(14)TFSI; efficiency calculation; solid electrolyte interphase (SEI); TERNARY POLYMER ELECTROLYTES; ELECTROCHEMICAL PROPERTIES; OXYGEN BATTERY; ELECTRODES; SEI; CYCLABILITY; PERFORMANCE; EFFICIENCY; CATHODE; SYSTEMS;

D O I：

10.3390/ijms15058122

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

In this work, the electrochemical stability and lithium plating/stripping performance of N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide (Pyr(14)TFSI) are reported, by investigating the behavior of Li metal electrodes in symmetrical Li/electrolyte/Li cells. Electrochemical impedance spectroscopy measurements and galvanostatic cycling at different temperatures are performed to analyze the influence of temperature on the stabilization of the solid electrolyte interphase (SEI), showing that TFSI-based ionic liquids (ILs) rank among the best candidates for long-lasting Li-air cells.

引用

页码：8122 / 8137

页数：16

共 52 条

[11] The Lithium-Oxygen Battery with Ether-Based Electrolytes [J].

Freunberger, Stefan A. ;

Chen, Yuhui ;

Drewett, Nicholas E. ;

Hardwick, Laurence J. ;

Barde, Fanny ;

Bruce, Peter G. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (37) :8609-8613

[12] Reactions in the Rechargeable Lithium-O2 Battery with Alkyl Carbonate Electrolytes [J].

Freunberger, Stefan A. ;

Chen, Yuhui ;

Peng, Zhangquan ;

Griffin, John M. ;

Hardwick, Laurence J. ;

Barde, Fanny ;

Novak, Petr ;

Bruce, Peter G. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (20) :8040-8047

[13] Lithium - Air Battery: Promise and Challenges [J].

Girishkumar, G. ;

McCloskey, B. ;

Luntz, A. C. ;

Swanson, S. ;

Wilcke, W. .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (14) :2193-2203

[14] The Role of Charge Reactions in Cyclability of Lithium-Oxygen Batteries [J].

Guo, Xiangxin ;

Zhao, Ning .

ADVANCED ENERGY MATERIALS, 2013, 3 (11) :1413-1416

[15] X-ray photoelectron spectroscopy of negative electrodes from high-power lithium-ion cells showing various levels of power fade [J].

Herstedt, M ;

Abraham, DP ;

Kerr, JB ;

Edström, K .

ELECTROCHIMICA ACTA, 2004, 49 (28) :5097-5110

[16] Evaluation and analysis of Li-air battery using ether-functionalized ionic liquid [J].

Higashi, Shougo ;

Kato, Yuichi ;

Takechi, Kensuke ;

Nakamoto, Hirofumi ;

Mizuno, Fuminori ;

Nishikoori, Hidetaka ;

Iba, Hideki ;

Asaoka, Takahiko .

JOURNAL OF POWER SOURCES, 2013, 240 :14-17

[17] Characterization of the lithium surface in N-methyl-N-alkylpyrrolidinium bis(trifluoromethanesulfonyl) amide room-temperature ionic liquid electrolytes [J].

Howlett, PC ;

Brack, N ;

Hollenkamp, AF ;

Forsyth, M ;

MacFarlane, DR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (03) :A595-A606

[18] High lithium metal cycling efficiency in a room-temperature ionic liquid [J].

Howlett, PC ;

MacFarlane, DR ;

Hollenkamp, AF .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (05) :A97-A101

[19] Pure ionic liquid electrolytes compatible with a graphitized carbon negative electrode in rechargeable lithium-ion batteries [J].

Ishikawa, Masashi ;

Sugimoto, Toshinori ;

Kikuta, Manabu ;

Ishiko, Eriko ;

Kono, Michiyuki .

JOURNAL OF POWER SOURCES, 2006, 162 (01) :658-662

[20]

Jung H., 2012, NAT CHEM, V4, P1

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