Carbonized Eggshell Membrane as a Natural Polysulfide Reservoir for Highly Reversible Li-S Batteries

被引：372

作者：

Chung, Sheng-Heng ^{[1
,2
]}

Manthiram, Arumugam ^{[1
,2
]}

机构：

[1] Univ Texas Austin, Electrochem Energy Lab, Austin, TX 78712 USA

[2] Univ Texas Austin, Mat Sci & Engn Program, Austin, TX 78712 USA

来源：

ADVANCED MATERIALS | 2014年 / 26卷 / 09期

关键词：

LITHIUM-SULFUR BATTERIES; CATHODE; PERFORMANCE;

D O I：

10.1002/adma.201304365

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbonized sucrose-coated eggshell membranes (CSEMs) consisting of natural micropores function well as a polysulfide reservoir in Li/dissolved polysulfide cells. The bottom CSEM current collector encapsulates the active material, while the upper CSEM inhibitor intercepts the migrating polysulfides. This design with CSEM allows the dissolved polysulfides to be localized and the electrochemical reactions within the cathode region to be stabilized, resulting in high discharge capacity, long-term cycle stability, and high sulfur loading.

引用

页码：1360 / 1365

页数：6

共 29 条

[1] Li/S fundamental chemistry and application to high-performance rechargeable batteries
Akridge, JR
Mikhaylik, YV
White, N
[J]. SOLID STATE IONICS, 2004, 175 (1-4) : 243 - 245
[2] Importance of structural and chemical heterogeneity of activated carbon surfaces for adsorption of dibenzothiophene
Ania, CO
Bandosz, TJ
[J]. LANGMUIR, 2005, 21 (17) : 7752 - 7759
[3] Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/nmat3191, 10.1038/NMAT3191]
[4] Lithium-sulfur batteries with superior cycle stability by employing porous current collectors
Chung, Sheng-Heng
Manthiram, Arumugam
[J]. ELECTROCHIMICA ACTA, 2013, 107 : 569 - 576
[5] Nano-cellular carbon current collectors with stable cyclability for Li-S batteries
Chung, Sheng-Heng
Manthiram, Arumugam
[J]. JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (34) : 9590 - 9596
[6] Dean J.A., 1985, LANGES HDB CHEM, V13
[7] Sulfur-Impregnated Activated Carbon Fiber Cloth as a Binder-Free Cathode for Rechargeable Li-S Batteries
Elazari, Ran
Salitra, Gregory
Garsuch, Arnd
Panchenko, Alexander
Aurbach, Doron
[J]. ADVANCED MATERIALS, 2011, 23 (47) : 5641 - +
[8] Highly Reversible Lithium/Dissolved Polysulfide Batteries with Carbon Nanotube Electrodes
Fu, Yongzhu
Su, Yu-Sheng
Manthiram, Arumugam
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (27) : 6930 - 6935
[9] Advances in Li-S batteries
Ji, Xiulei
Nazar, Linda F.
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (44) : 9821 - 9826
[10] Ji XL, 2009, NAT MATER, V8, P500, DOI [10.1038/NMAT2460, 10.1038/nmat2460]

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