High valence 3p and transition metal based MOFs

被引:443
作者
Devic, Thomas [1 ]
Serre, Christian [1 ]
机构
[1] Univ Versailles St Quentin Yvelines, UMR CNRS 8180, Inst Lavoisier, F-78035 Versailles, France
关键词
MICROPOROUS COORDINATION POLYMERS; AUTOMATED DIFFRACTION TOMOGRAPHY; ORGANIC FRAMEWORKS ZMOFS; HYBRID OPEN FRAMEWORKS; SOLID-STATE NMR; HYDROTHERMAL SYNTHESIS; BUILDING-BLOCKS; THERMAL-STABILITY; CRYSTAL-STRUCTURE; GIANT PORES;
D O I
10.1039/c4cs00081a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This article focuses on high valence 3p and transition metal based metal organic frameworks. In the first part we will discuss the complex solution chemistry of these metals which makes this sub-class of MOFs more of a challenge than the traditional low valence metal based MOFs. This is followed by a short review of the different classes of solids based on phosphonates, carboxylates and other linkers. Finally, we report some of the most relevant properties of these solids such as their chemical or thermal stability as well as their catalytic, redox- and photo-activities.
引用
收藏
页码:6097 / 6115
页数:19
相关论文
共 234 条
[1]   [Al4(OH)2(OCH3)4(H2N-bdc)3]•xH2O: A 12-Connected Porous Metal-Organic Framework with an Unprecedented Aluminum-Containing Brick [J].
Ahnfeldt, Tim ;
Guillou, Nathalie ;
Gunzelmann, Daniel ;
Margiolaki, Irene ;
Loiseau, Thierry ;
Ferey, Gerard ;
Senker, Juergen ;
Stock, Norbert .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (28) :5163-5166
[2]   Cellulose Hydrolysis by a New Porous Coordination Polymer Decorated with Sulfonic Acid Functional Groups [J].
Akiyama, George ;
Matsuda, Ryotaro ;
Sato, Hiroshi ;
Takata, Masaki ;
Kitagawa, Susumu .
ADVANCED MATERIALS, 2011, 23 (29) :3294-+
[3]   ZIRCONIUM PHOSPHITE (3,3',5,5'-TETRAMETHYLBIPHENYL)DIPHOSPHONATE, A MICROPOROUS, LAYERED, INORGANIC-ORGANIC POLYMER [J].
ALBERTI, G ;
COSTANTINO, U ;
MARMOTTINI, F ;
VIVANI, R ;
ZAPPELLI, P .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (09) :1357-1359
[4]   CRYSTALLINE ZR(R-PO3)2 AND ZR(R-OPO3)2 COMPOUNDS (R=ORGANIC RADICAL) - NEW CLASS OF MATERIALS HAVING LAYERED STRUCTURE OF ZIRCONIUM-PHOSPHATE TYPE [J].
ALBERTI, G ;
COSTANTINO, U ;
ALLULLI, S ;
TOMASSINI, N .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1978, 40 (06) :1113-1117
[5]   In(OH)BDC•0.75BDCH2 (BDC = benzenedicarboxylate), a hybrid inorganic-organic vernier structure [J].
Anokhina, EV ;
Vougo-Zanda, M ;
Wang, XQ ;
Jacobson, AJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (43) :15000-15001
[6]  
[Anonymous], 2009, CHEM SOC REV, V38, P1201, DOI DOI 10.1039/B906666G
[7]  
[Anonymous], 2012, CHEM REV, V112
[8]   Characterisation and properties of the n=3 and n=4 members of the Al2[O3PCnH2nPO3](H2O)2F2 framework aluminium alkylenediphosphonate series [J].
Attfield, Martin P. ;
Mendieta-Tan, Carlos ;
Yuan, Zhanhui ;
Clegg, William .
SOLID STATE SCIENCES, 2008, 10 (09) :1124-1131
[9]   Postsynthetic Modification Switches an Achiral Framework to Catalytically Active Homochiral Metal-Organic Porous Materials [J].
Banerjee, Mainak ;
Das, Sunirban ;
Yoon, Minyoung ;
Choi, Hee Jung ;
Hyun, Myung Ho ;
Park, Se Min ;
Seo, Gon ;
Kim, Kimoon .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (22) :7524-+
[10]   VIII(OH){O2C-C6H4-CO2}•(HO2C-C6H4-CO2H)x(DMF)y(H2O)z (or MIL-68), a new vanadocarboxylate with a large pore hybrid topology:: reticular synthesis with infinite inorganic building blocks? [J].
Barthelet, K ;
Marrot, J ;
Férey, G ;
Riou, D .
CHEMICAL COMMUNICATIONS, 2004, (05) :520-521