A general approach towards 2-substituted 3-hydroxy propanoates; Application to the synthesis of methyl tropinate

被引：16

作者：

Imogai, H ^{[1
]}

Larcheveque, M ^{[1
]}

机构：

[1] ENSCP,CNRS,SYNTH ORGAN LAB,F-75231 PARIS 05,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 06期

关键词：

D O I：

10.1016/S0957-4166(97)00063-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantiomerically pure R or S 2-substituted 3-hydroxy propanoates may be prepared by regioselective BF3 promoted opening of homochiral styrene oxide by lithium cyanocuprates followed by oxidative cleavage of the aromatic moiety with catalytic ruthenium trichloride. (C) 1997 Elsevier Science Ltd.

引用

页码：965 / 972

页数：8

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