Flower-like In2O3 Nanostructures Derived from Novel Precursor: Synthesis, Characterization, and Formation Mechanism

被引：70

作者：

Wang, Cuiqing ^{[1
]}

Chen, Dairong ^{[1
]}

Jiao, Xuling ^{[1
]}

机构：

[1] Shandong Univ, Sch Chem & Chem Engn, Key Lab Special Funct Aggregate Mat, Educ Minist, Jinan 250100, Peoples R China

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2009年 / 113卷 / 18期

基金：

中国国家自然科学基金;

关键词：

INDIUM-OXIDE NANOPARTICLES; OPTICAL-PROPERTIES; PHOTOLUMINESCENCE PROPERTIES; NANOCRYSTAL CHAINS; MESOPOROUS SILICA; CATALYTIC GROWTH; VAPOR TRANSPORT; HOLLOW SPHERES; TIN OXIDE; CRYSTALLINE;

D O I：

10.1021/jp809855d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Three-dimensional flower-like In2O3 nanostructures with a uniform diameter of ca. 0.7-1.2 mu m were fabricated via the glycerol-mediated solvothermal reaction followed by calcination. The flower-like indium precursor and In2O3 nanostructures were investigated in detail, and the as-formed indium precursor could be transformed to cubic In2O3 maintaining its original flower-like morphology after calcination. The formation mechanism, which included the formation of In(OH)(3) nanoparticles and their aggregation as well as the reaction between In(OH)(3) and glycerol, was proposed. In addition, the room-temperature photoluminescence (PL) spectrum of the In2O3 nanostructure showed peculiar visible emissions.

引用

页码：7714 / 7718

页数：5

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