Synthesis of unsymmetrical 1,1′-disubstituted ferrocenes.: Formation of ferrocenophanes via intramolecular cycloaddition

被引:21
作者
Argyropoulos, N [1 ]
Coutouli-Argyropoulou, E [1 ]
机构
[1] Aristotle Univ Thessaloniki, Dept Chem, Organ Chem Lab, GR-54006 Thessaloniki, Greece
关键词
unsymmetrical disubstituted ferrocenes; ferrocenophanes; intramolecular cycloadditions; nitrones;
D O I
10.1016/S0022-328X(02)01394-3
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Unsymmetrical 1,1'-disubstituted ferrocenes bearing appropriate substituents for intramolecular cycloadditions were synthesized conveniently starting from 1,1'-ferrocenedicarbaldehyde. Ferrocenenitrone derivatives reacted in an intramolecular regioselective manner affording ferrocenophanes. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:117 / 122
页数:6
相关论文
共 35 条
  • [1] A NEW METHOD FOR STEREOSELECTIVE HOMOALLYLIC AMINE SYNTHESIS
    ARMSTRONG, SK
    COLLINGTON, EW
    KNIGHT, JG
    NAYLOR, A
    WARREN, S
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1993, (13): : 1433 - 1447
  • [2] AN IMPROVED SYNTHESIS OF FERROCENE-1,1'-DICARBALDEHYDE
    BALAVOINE, GGA
    DOISNEAU, G
    FILLEBEENKHAN, T
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 412 (03) : 381 - 382
  • [3] Efficient regio- and diastereo-controlled synthesis of 1,1′- and 1,1′,2,2′-functionalised ferrocenes and the formation of 2-oxa[3]ferrocenophanes
    Carroll, MA
    White, AJP
    Widdowson, DA
    Williams, DJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2000, (10): : 1551 - 1557
  • [4] Chiffre J, 2001, EUR J INORG CHEM, P2221
  • [5] Electrochemical studies of ferrocene derivatives and their complexation by β-cyclodextrin
    Coutouli-Argyropoulou, E
    Kelaidopoulou, A
    Sideris, C
    Kokkinidis, G
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 477 (02) : 130 - 139
  • [6] Formation and cycloaddition reactions of ferrocenyl nitrones
    Coutouli-Argyropoulou, E
    Sabbas, I
    Konarski, S
    [J]. JOURNAL OF HETEROCYCLIC CHEMISTRY, 2000, 37 (05) : 1055 - 1060
  • [7] 1,3-dipolar cycloaddition reactions of isothiazol-3(2H)-ones with nitrile oxides. An unexpected site selectivity of the carbonyl bond of 5-benzoyl-isothiazol-3(2H)-one
    CoutouliArgyropoulou, E
    Anastasopoulos, C
    [J]. JOURNAL OF HETEROCYCLIC CHEMISTRY, 1996, 33 (03) : 731 - 733
  • [8] 1,3-DIPOLAR CYCLOADDITION OF NITRILE OXIDES WITH 2-PHENYL-4-ETHOXYMETHYLENE-5(4H)-OXAZOLONE
    COUTOULIARGYROPOULOU, E
    THESSALONIKEOS, E
    [J]. JOURNAL OF HETEROCYCLIC CHEMISTRY, 1992, 29 (01) : 251 - 253
  • [9] Formation and reduction reactions of 3-indol-3-yl-isoxazolidines
    CoutouliArgyropoulou, E
    MalamidouXenikaki, E
    Stampelos, XN
    Alexopoulou, IN
    [J]. TETRAHEDRON, 1997, 53 (02) : 707 - 718
  • [10] A novel method to synthesize asymmetrical disubstituted ferrocenes
    Dong, TY
    Lai, LL
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 509 (02) : 131 - 134