Infrared imaging of single nanoparticles via strong field enhancement in a scanning nanogap

被引:87
作者
Cvitkovic, A. [1 ]
Ocelic, N.
Aizpurua, J.
Guckenberger, R.
Hillenbrand, R.
机构
[1] Max Planck Inst Biochem, Nano Photon Grp, D-82152 Martinsried, Germany
[2] Max Planck Inst Biochem, Abt Mol Strukturbiol, D-82152 Martinsried, Germany
[3] Donostia Int Phys Ctr, San Sebastian 20018, Spain
关键词
D O I
10.1103/PhysRevLett.97.060801
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We demonstrate nanoscale resolved infrared imaging of single nanoparticles employing near-field coupling in the nanoscopic gap between the metal tip of a scattering-type near-field optical microscope and the substrate supporting the particles. Experimental and theoretical evidence is provided that highly reflecting or polariton-resonant substrates strongly enhance the near-field optical particle contrast. Using Si substrates we succeeded in detecting Au particles as small as 8 nm (<lambda/1000) at midinfrared wavelengths of about lambda=10 mu m. Our results open the door to infrared spectroscopy of individual nanoparticles, nanocrystals, or macromolecules.
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页数:4
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共 31 条
[1]   THE EFFECTS OF THE INTERACTION BETWEEN RESONANCES IN THE ELECTROMAGNETIC RESPONSE OF A SPHERE-PLANE STRUCTURE - APPLICATIONS TO SURFACE ENHANCED SPECTROSCOPY [J].
ARAVIND, PK ;
METIU, H .
SURFACE SCIENCE, 1983, 124 (2-3) :506-528
[2]   Surface plasmon subwavelength optics [J].
Barnes, WL ;
Dereux, A ;
Ebbesen, TW .
NATURE, 2003, 424 (6950) :824-830
[3]   Optical nonlinearity versus mechanical anharmonicity contrast in dynamic mode apertureless scanning near-field optical microscopy [J].
Bek, A ;
Vogelgesang, R ;
Kern, K .
APPLIED PHYSICS LETTERS, 2005, 87 (16) :1-3
[4]   Infrared spectroscopic mapping of single nanoparticles and viruses at nanoscale resolution [J].
Brehm, Markus ;
Taubner, Thomas ;
Hillenbrand, Rainer ;
Keilmann, Fritz .
NANO LETTERS, 2006, 6 (07) :1307-1310
[5]   Optical antennas: Resonators for local field enhancement [J].
Crozier, KB ;
Sundaramurthy, A ;
Kino, GS ;
Quate, CF .
JOURNAL OF APPLIED PHYSICS, 2003, 94 (07) :4632-4642
[6]  
de Abajo FJG, 1998, PHYS REV LETT, V80, P5180
[7]  
Edwards D.F., 1985, Handbook of optical constants of solids
[8]   Single quantum dot coupled to a scanning optical antenna: A tunable superemitter [J].
Farahani, JN ;
Pohl, DW ;
Eisler, HJ ;
Hecht, B .
PHYSICAL REVIEW LETTERS, 2005, 95 (01)
[9]   High-resolution imaging of single fluorescent molecules with the optical near-field of a metal tip [J].
Frey, HG ;
Witt, S ;
Felderer, K ;
Guckenberger, R .
PHYSICAL REVIEW LETTERS, 2004, 93 (20) :200801-1
[10]   Electrodynamics of spatial clusters of spheres: Substrate effects [J].
Gozhenko, VV ;
Grechko, LG ;
Whites, KW .
PHYSICAL REVIEW B, 2003, 68 (12)