Catalytic aerobic oxidative decarboxylation of α-trifluoromethyl-α-hydroxy acids to trifluoromethyl ketones

被引：27

作者：

Blay, G ^{[1
]}

Fernández, I ^{[1
]}

Marco-Aleixandre, A ^{[1
]}

Monje, B ^{[1
]}

Pedro, JR ^{[1
]}

Ruiz, R ^{[1
]}

机构：

[1] Univ Valencia, Fac Quim, Dept Quim Organ, E-46100 Burjassot, Valencia, Spain

来源：

TETRAHEDRON | 2002年 / 58卷 / 42期

关键词：

decarboxylation; catalysts; fluorine compounds; cobalt; complexes;

D O I：

10.1016/S0040-4020(02)00947-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidative decarboxylation of alpha-trifluoromethyl-alpha-hydroxy acids to trifluoromethyl ketones is carried out under mild catalytic aerobic conditions using a cobalt(Ill) complex in the presence of pivalaldehyde. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：8565 / 8571

页数：7

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