Calix[6]arene derived diphosphite, synthesis and complexation behaviour; X-ray structure of a palladium(II) chloride complex

被引：22

作者：

Parlevliet, FJ

Olivier, A

deLange, WGJ

Kamer, PCJ

Kooijman, H

Spek, AL

vanLeeuwen, PWNM

机构：

[1] UNIV AMSTERDAM, DEPT INORGAN CHEM, 1018 WV AMSTERDAM, NETHERLANDS

[2] UNIV UTRECHT, BIJVOET CTR BIOMOL RES CRYSTAL & STRUCT CHEM, 3584 CH UTRECHT, NETHERLANDS

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 05期

关键词：

D O I：

10.1039/cc9960000583

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Calix[6]arene reacts with 2 equiv. of PCl3 to form a bidentate diphosphite ligand L which coordinates to Pd, Pt and Re in a cis fashion and, according to X-ray analysis, with a bite angle of approximately 90 degrees for a palladium complex [PdCl(2)L].

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收藏

页码：583 / 584

页数：2

相关论文

共 17 条

[1] SPIRODIENONE ROUTE FOR AMINODEHYDROXYLATION - MONOAMINOTRIHYDROXY-P-TERT-BUTYLCALIX[4]ARENE [J].

ALEKSIUK, O ;

GRYNSZPAN, F ;

BIALI, SE .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (08) :1994-1996

[2] QUICK SYNTHESIS OF THE 1ST DOUBLE PORPHYRIN DOUBLE CALIX[4]ARENE [J].

ASFARI, Z ;

VICENS, J ;

WEISS, J .

TETRAHEDRON LETTERS, 1993, 34 (04) :627-628

[3] HYDRIDORHODIUM DIPHOSPHITE CATALYSTS IN THE ASYMMETRIC HYDROFORMYLATION OF STYRENE [J].

BUISMAN, GJH ;

VOS, EJ ;

KAMER, PCJ ;

VANLEEUWEN, PWNM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (03) :409-417

[4] TRANSITION-METAL COMPLEXES OF LOWER RIM 1,3-DIPHOSPHINITE AND 1,3-DIPHOSPHINO CALIX[4]ARENES [J].

CAMERON, BR ;

VANVEGGEL, FCJM ;

REINHOUDT, DN .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (09) :2802-2806

[5] DIPHOSPHINES WITH NATURAL BITE ANGLES NEAR 120-DEGREES INCREASE SELECTIVITY FOR NORMAL-ALDEHYDE FORMATION IN RHODIUM-CATALYZED HYDROFORMYLATION [J].

CASEY, CP ;

WHITEKER, GT ;

MELVILLE, MG ;

PETROVICH, LM ;

GAVNEY, JA ;

POWELL, DR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (14) :5535-5543

[6] SHAPING CALIX[8]ARENE FRAMEWORK BY INTRAMOLECULAR BRIDGING - SYNTHESIS OF CONFORMATIONALLY BLOCKED CALIX[8]ARENE DERIVATIVES [J].

CUNSOLO, F ;

PIATTELLI, M ;

NERI, P .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (17) :1917-1918

[7] FACILE SYNTHETIC ROUTE TO CONE-SHAPED PHOSPHORYLATED [CH2P(O)PH(2)] CALIX[4]ARENES [J].

DIELEMAN, C ;

LOEBER, C ;

MATT, D ;

DECIAN, A ;

FISCHER, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (18) :3097-3100

[8] PHOSPHORUS POLYBRIDGED CALIXARENES [J].

GRYNSZPAN, F ;

ALEKSIUK, O ;

BIALI, SE .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (01) :13-16

[9] DIRECT TRANSFORMATION OF 6-COORDINATE TO 3-COORDINATE PHOSPHORUS IN PARA-TERT-BUTYLCALIX[4]ARENE - THE 1ST X-RAY CRYSTAL-STRUCTURE OF A HYPERVALENT MAIN GROUP ATOM BOUND TO A CALIXARENE [J].

KHASNIS, DV ;

BURTON, JM ;

LATTMAN, M ;

ZHANG, HM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (08) :562-563

[10]

LOEBER C, 1995, B SOC CHIM FR, V132, P166