Models for oxidation catalyst: Characterization and reaction at the atomic level

被引：25

作者：

Freund, H. -J. ^{[1
]}

机构：

[1] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany

来源：

CATALYSIS TODAY | 2006年 / 117卷 / 1-3期

关键词：

model catalysts; nanoparticles; molecular beam; vibrational spectroscopy; structure-spectroscopic relations;

D O I：

10.1016/j.cattod.2006.05.043

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Three case studies to demonstrate the ability to characterize oxidation model catalysts and reactions of these systems at the atomic level are reviewed. Firstly, results on small Au aggregates on a clean MgO(100) surface which are interesting model systems for low temperature oxidation are considered. Secondly, oxidative dehydrogenation of methanol on alumina-supported Pd is addressed. The problem of oxygen storage in and on the Pd particles is studied for nanoparticles on Fe3O4(111). Finally, morphology-spectroscopy relations for oxide-supported so-called monolayer vanadia catalysts are investigated. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：6 / 14

页数：9

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