Palladium-catalyzed decarboxylation and decarbonylation under hydrothermal conditions: Decarboxylative deuteration

被引：119

作者：

Matsubara, S ^{[1
]}

Yokota, Y ^{[1
]}

Oshima, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6158510, Japan

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 12期

关键词：

D O I：

10.1021/ol0492602

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Decarboxylation of free carboxylic acid was performed by Pd/C catalyst under hydrothermal water (250 degreesC/4 MPa). Under the hydrothermal conditions of deuterium oxide, decarbonylative deuteration was observed to give fully deuterated hydrocarbons from carboxylic acids or aldehydes.

引用

页码：2071 / 2073

页数：3

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