Prussian blue analogues Mn[Fe(CN)6]0.6667•nH2O cubes as an anode material for lithium-ion batteries

被引：120

作者：

Xiong, Peixun ^{[1
,2
]}

Zeng, Guojin ^{[1
,2
]}

Zeng, Lingxing ^{[1
,2
]}

Wei, Mingdeng ^{[1
,2
]}

机构：

[1] Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China

[2] Fuzhou Univ, Inst Adv Energy Mat, Fuzhou 350002, Fujian, Peoples R China

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 38期

基金：

中国国家自然科学基金; 高等学校博士学科点专项科研基金;

关键词：

METAL-ORGANIC-FRAMEWORKS; MAGNETIC-PROPERTIES; HEXACYANOFERRATE NANOPARTICLES; ELECTRODE MATERIALS; CATHODE MATERIAL; ENERGY-STORAGE; CARBON; ELECTROCHEMISTRY; NANOSTRUCTURES; BEHAVIOR;

D O I：

10.1039/c5dt03030g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the present work, Prussian blue analogues, Mn[Fe(CN)(6)](0.6667)center dot nH(2)O (Mn-PBA), were synthesized by a simple synthetic route and characterized by XRD, SEM, TEM, FTIR and TGA. When this material was firstly used as an anode for lithium-ion batteries, it exhibited a large capacity, good rate capability and cycling stability with a high Coulombic efficiency. For instance, a reversible capacity of 295.7 mA h g(-1) can be achieved after 100 cycles at 200 mA g(-1).

引用

页码：16746 / 16751

页数：6

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